The three-dimensional configuration of the ester heterocycle is basically the same as that of the carbocycle. Compound: (R)-4-(tert-Butyl)-2-(5-(trifluoromethyl)pyridin-2-yl)-4,5-dihydrooxazole(SMILESS: FC(C1=CN=C(C2=N[C@H](C(C)(C)C)CO2)C=C1)(F)F,cas:1428537-19-2) is researched.Product Details of 2199-44-2. The article 《Alkenyl Carbonyl Derivatives in Enantioselective Redox Relay Heck Reactions: Accessing α,β-Unsaturated Systems》 in relation to this compound, is published in Journal of the American Chemical Society. Let’s take a look at the latest research on this compound (cas:1428537-19-2).
A highly enantioselective and site-selective Pd-catalyzed arylation of alkenes linked to carbonyl derivatives to yield α,β-unsaturated systems is reported. The high site selectivity is attributed to both a solvent effect and the polarized nature of the carbonyl group, both of which have been analyzed through multidimensional anal. tools. The reaction can be performed in an iterative fashion allowing for a diastereoselective installation of two aryl groups along an alkyl chain.
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Reference:
Thiazolidine – Wikipedia,
Thiazolidine – ScienceDirect.com