Recently I am researching about CATALYTIC ENANTIOSELECTIVE ADDITION; ASYMMETRIC ALLYLATION; MEDIATED CYCLIZATION; CONJUGATE ALLYLATION; HOMOALLYLIC AMINES; AROMATIC-ALDEHYDES; CARBONYL-COMPOUNDS; GALLIUM CHLORIDE; ALLYLSILANES; MERCURY, Saw an article supported by the National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [81660576]; Ministry of Education (PCSIRT)Program for Changjiang Scholars & Innovative Research Team in University (PCSIRT); Fundamental Research Funds for the Central UniversitiesFundamental Research Funds for the Central Universities. Published in ROYAL SOC CHEMISTRY in CAMBRIDGE ,Authors: Gong, Y; Cao, ZY; Shi, YB; Zhou, F; Zhou, Y; Zhou, J. The CAS is 94-41-7. Through research, I have a further understanding and discovery of Chalcone. Safety of Chalcone
It is reported that cheap and easily available Hg(OTf)(2) can efficiently mediate the Sakurai-Hosomi reaction of N-tert-butyloxycarbonyl (Boc) amino sulfones, aldehydes, and alpha-fluoroalkyl ketones using allyltrimethylsilane, with the catalyst loading down to 0.5-5.0 mol%, enabling the facile access to synthetically valuable homoallylic alcohols or amines, respectively. A chemoselective 1,4-allylation of alpha,beta-unsaturated enones is also achieved under the catalysis of 5.0 mol% Hg(OTf)(2). In most cases, Hg(OTf)(2) exhibited intriguing properties superior to those of commonly used metal Lewis acids for such reactions, suggesting that mercury catalysis is worthwhile to explore.
Safety of Chalcone. About Chalcone, If you have any questions, you can contact Gong, Y; Cao, ZY; Shi, YB; Zhou, F; Zhou, Y; Zhou, J or concate me.
Reference:
Thiazolidine – Wikipedia,
,Thiazolidine – ScienceDirect.com