Application In Synthesis of Bromoferrocene. So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic. Compound: Bromoferrocene, is researched, Molecular C10BrFe, CAS is 1273-73-0, about Synthesis, X-ray structure and chemical properties of 17α-ferrocenylestradiol.
The X-ray structure of 17α-ferrocenylestradiol shows that the ferrocenyl group is at the α-position of the steroid, below the plane of the D ring. From acidic medium it is possible to obtain and isolate the derivative with a carbenium ion in 17-α position. This ion is transformed by various nucleophiles into the C(16)-C(17)-unsaturated derivative With NaBH4 in acidic medium the reduction leads to a mixture of 17α- and 17β-ferrocenylestrol with a predominance of the β product, owing to a more favorable entrance of hydride in the α position. The oxidized derivative 17α-ferrociniumylestradiol tetrafluoroborate was prepared and its properties are described.
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Reference:
Thiazolidine – Wikipedia,
Thiazolidine – ScienceDirect.com