An article Intercepted dehomologation of aldoses by N-heterocyclic carbene catalysis – a novel transformation in carbohydrate chemistry WOS:000489645500033 published article about INDIUM-MEDIATED ALLYLATION; ALDEHYDES; CHAIN in [Draskovits, Markus; Kalaus, Hubert; Stanetty, Christian; Mihovilovic, Marko D.] TU Wien, Inst Appl Synthet Chem, A-1060 Vienna, Austria in 2019.0, Cited 42.0. Quality Control of Chalcone. The Name is Chalcone. Through research, I have a further understanding and discovery of 94-41-7
The development of an N-heterocyclic carbene (NHC) catalysed intercepted dehomologation of aldoses is reported. The unique selectivity of NHCs for aldehydes is exploited in the complex context of reducing sugars. Examples of strong substrate governance for either intercepted dehomologation or a subsequent redox-lactonisation were identified and mechanistically understood. More importantly, it was shown that catalyst design allowed the tuning of the selectivity of the reaction with structurally unbiased starting materials towards either of the two scenarios.
Quality Control of Chalcone. About Chalcone, If you have any questions, you can contact Draskovits, M; Kalaus, H; Stanetty, C; Mihovilovic, MD or concate me.
Reference:
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