The preparation of ester heterocycles mostly uses heteroatoms as nucleophilic sites, which are achieved by intramolecular substitution or addition reactions. Compound: Bromoferrocene( cas:1273-73-0 ) is researched.Computed Properties of C10BrFe.Sasamori, Takahiro; Kobayashi, Megumi; Nagahora, Noriyoshi; Sugiyama, Yusuke; Tokitoh, Norihiro published the article 《Synthesis and characterization of functionalized ferrocenylsilanes bearing a bulky substituent》 about this compound( cas:1273-73-0 ) in Silicon Chemistry. Keywords: sterically crowded ferrocenylsilane preparation crystal mol structure electrochem redox; DFT calculation hindered ferrocenylsilanediol. Let’s learn more about this compound (cas:1273-73-0).
Several types of overcrowded ferrocenylsilanes, Tbt(Fc)SiX2(Tbt = 2,4,6-tris[bis(trimethylsilyl)methyl]phenyl, Fc = ferrocenyl, X = H, OH, Br) were synthesized and characterized. In addition, DFT calculations for ferrocenylsilanediol systems indicated the existence of the intramol. hydrogen bonding between the Fe atom and H-O moiety in Tbt(Fc)Si(OH)2.
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Reference:
Thiazolidine – Wikipedia,
Thiazolidine – ScienceDirect.com