Recently I am researching about ALPHA-ALKYLATION; C-ALKYLATION; KETONES; ALCOHOLS; AMIDES; DEHYDROGENATION; NANOPALLADIUM; COMPLEXES; ESTERS, Saw an article supported by the Macquarie University through the International Macquarie University Research Excellence Scholarship (iMQRES) program. Published in ROYAL SOC CHEMISTRY in CAMBRIDGE ,Authors: Wang, DF; McBurney, RT; Pernik, I; Messerle, BA. The CAS is 94-41-7. Through research, I have a further understanding and discovery of Chalcone. Recommanded Product: Chalcone
The catalytic alkylation of ketones with alcohols via the hydrogen borrowing methodology (HB) has the potential to be a highly efficient approach for forming new carbon-carbon bonds. However, this transformation can result in more than one product being formed. The work reported here utilises bidentate triazole-carbene ligated iridium and rhodium complexes as catalysts for the selective formation of alkylated ketone or alcohol products. Switching from an iridium centre to a rhodium centre in the complex resulted in significant changes in product selectivity. Other factors – base, base loading, solvent and reaction temperature – were also investigated to tune the selectivity further. The optimised conditions were used to demonstrate the scope of the reaction across 17 ketones and 14 alcohols containing a variety of functional groups. A series of mechanistic investigations were performed to probe the reasons behind the product selectivity, including kinetic and deuterium studies.
Recommanded Product: Chalcone. Welcome to talk about 94-41-7, If you have any questions, you can contact Wang, DF; McBurney, RT; Pernik, I; Messerle, BA or send Email.
Reference:
Thiazolidine – Wikipedia,
,Thiazolidine – ScienceDirect.com