Application of 1273-73-0. Aromatic heterocyclic compounds can also be classified according to the number of heteroatoms contained in the heterocycle: single heteroatom, two heteroatoms, three heteroatoms and four heteroatoms. Compound: Bromoferrocene, is researched, Molecular C10BrFe, CAS is 1273-73-0, about Electrochemical Parameterization in Sandwich Complexes of the First Row Transition Metals. Author is Lu, Shuangxing; Strelets, Vladimir V.; Ryan, Matthew F.; Pietro, William J.; Lever, A. B. P..
Applying the ligand electrochem. parameter approach to sandwich complexes and standardizing to the FeIII/FeII couple, the authors obtained EL(L) values for over 200 π-ligands. Linear correlations exist between formal potential (E°) and the ∑EL(L) for each metal couple. In this fashion, the authors report correlation data for many first row transition metal couples. The correlations between the EL(L) of the substituted π-ligand and the Hammett substituent constants (σp) are also explored.
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Reference:
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