Some scientific research about (S)-4-Isopropylthiazolidine-2-thione

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Synthetic Route of 76186-04-4, A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 76186-04-4, Name is (S)-4-Isopropylthiazolidine-2-thione, molecular formula is C6H11NS2. In a Article£¬once mentioned of 76186-04-4

Expeditious Asymmetric Synthesis of Optically Pure delta-Lactones Bearing Consecutive Three Asymmetric Centers

The (4S)-isopropyl-1,3-thiazolidine-2-thione diamides of 3-substituted glutaric acids were submitted to enolization with Sn(CF3SO3)2 and N-ethylpiperidine.The resultant tin(II) enolate was treated with several aldehydes to give the aldols, which readily undergo basic lactonization affording the corresponding chiral delta-lactones bearing consecutive three asymmetric centers.

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Reference£º
Quinuclidine – Wikipedia,
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