76186-04-4, Name is (S)-4-Isopropylthiazolidine-2-thione, belongs to thiazolidine compound, is a common compound. Quality Control of (S)-4-Isopropylthiazolidine-2-thioneIn an article, once mentioned the new application about 76186-04-4.
Synthetic studies towards lagunamide C: Polyketide assembly investigations
Lagunamide C is a depsipeptide natural product with low nM cytotoxicity towards numerous cancer cell lines. Synthetically, it is disconnected to a pentapeptide backbone and polyketide unit that possesses four stereogenic centers, of which two of centers are in question (C38 & 40). Our model system highlights a high-selective aldol addition via a Crimmin’s auxiliary setting the C40 ester linkage, and a non-facially selective cyclopropanation with subsequent ring opening for the installation of the C38 methyl center.
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Reference£º
Quinuclidine – Wikipedia,
Quinuclidine | C7H727N | ChemSpider