The three-dimensional configuration of the ester heterocycle is basically the same as that of the carbocycle. Compound: Bromoferrocene(SMILESS: Br[C-]12[Fe+2]3456789([C-]%10C6=C7C8=C9%10)C1=C3C4=C25,cas:1273-73-0) is researched.Formula: C27H36Cl2N2. The article 《Stable σH-adducts in reactions of ferrocenyllithium with azines》 in relation to this compound, is published in Russian Chemical Bulletin. Let’s take a look at the latest research on this compound (cas:1273-73-0).
Stable σH-adducts as intermediates of the nucleophilic substitution of H in 3-(2-pyridyl)-1,2,4-triazines were obtained using ferrocenyllithium as a nucleophilic reagent. The 3D structures of the reaction products were established by an x-ray diffraction study on 1-[4-ethyl-6-phenyl-3-(2-pyridyl)-5(H)-1,2,4-triazin-5-yl]ferrocene [monoclinic, space group P21/c, a 9.3471(8), b 20.7674(13), c 10.7865(10) Å, β 96.248(7)°, V 2081.4(3) Å3, Z 4].
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Reference:
Thiazolidine – Wikipedia,
Thiazolidine – ScienceDirect.com