So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic.Labande, Agnes; Daran, Jean-Claude; Long, Nicholas J.; White, Andrew J. P.; Poli, Rinaldo researched the compound: Bromoferrocene( cas:1273-73-0 ).Category: thiazolidine.They published the article 《Rhodium(III) and ruthenium(II) complexes of redox-active, chelating N-heterocyclic carbene/thioether ligands》 about this compound( cas:1273-73-0 ) in New Journal of Chemistry. Keywords: crystal structure rhodium ruthenium ferrocenyl NHC thioether complex preparation; mol structure rhodium ruthenium ferrocenyl NHC thioether complex; rhodium ruthenium ferrocenyl NHC thioether complex preparation electrochem property. We’ll tell you more about this compound (cas:1273-73-0).
Half-sandwich rhodium(III) and ruthenium(II) complexes bearing a new redox-active ferrocenyl NHC-thioether ligand have been prepared The synthesis of ferrocenyl thioether-imidazolium salts was carried out via intermediate FcSCH2CH2Cl using an improved procedure. Rhodium(III) complex and ruthenium(II) complex were obtained in good yields and were fully characterised by NMR spectroscopy, x-ray diffraction anal. and electrochem. Rhodium(III) complex shows a complex ABCD system by 1H NMR, which denotes conformational rigidity due to the presence of several bulky groups. Electrochem. anal. by cyclic voltammetry reveals reversible redox behavior about the iron center in both complexes, and indicates electronic communication between iron and rhodium or ruthenium.
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Reference:
Thiazolidine – Wikipedia,
Thiazolidine – ScienceDirect.com