A novel chiral silver(I) complex from the reaction of thiazolidinethione with AgOAc was written by Shi, Min;Jiang, Jian-Kang;Zhao, Gui-Ling. And the article was included in European Journal of Inorganic Chemistry in 2002.Formula: C6H11NS2 This article mentions the following:
A novel chiral Ag(I) complex (Ag6L6) was successfully synthesized from the reaction of chiral (S)-4-isopropylthiazolidine-2-thione (L) with AgOAc in CH2Cl2 in the presence of Et3N and DMAP at room temperature The unique crystal structure of Ag6L6 was unambiguously disclosed by x-ray anal. The six Ag atoms and six (S)-4-isopropylthiazolidine-2-thione ligands present in the complex are connected through the S and N atoms to form a cluster containing a Ag octahedron with six faces of the octahedron capped by ligands. In the experiment, the researchers used many compounds, for example, (S)-4-Isopropylthiazolidine-2-thione (cas: 76186-04-4Formula: C6H11NS2).
(S)-4-Isopropylthiazolidine-2-thione (cas: 76186-04-4) belongs to thiazolidine derivatives. Thiazolidines undergo hydrolysis to aldehyde and amino thiol under acid or basic aqueous conditions. Thiazolidine is prepared as it was in its first reported synthesis, by the condensation of cysteamine and formaldehyde. Other thiazolidines may be synthesized by similar condensations. A notable derivative is 4-carboxythiazolidine, derived from formaldehyde and cysteine.Formula: C6H11NS2
Referemce:
Thiazolidine – Wikipedia,
Thiazolidine – ScienceDirect.com