Our Top Choice Compound: 1273-73-0

Here is just a brief introduction to this compound(1273-73-0)Electric Literature of C10BrFe, more information about the compound(Bromoferrocene) is in the article, you can click the link below.

Electric Literature of C10BrFe. The reaction of aromatic heterocyclic molecules with protons is called protonation. Aromatic heterocycles are more basic than benzene due to the participation of heteroatoms. Compound: Bromoferrocene, is researched, Molecular C10BrFe, CAS is 1273-73-0, about Triferrocenyl complexes of tungsten(VI): the molecular structure in the solid state and dynamic behavior in solution of triferrocenyl(ferrocenyloxy)oxotungsten, WO(OFc)Fc3. Author is Herberhold, Max; Kniesel, Heidemarie; Haumaier, Ludwig; Thewalt, Ulf.

WO(X)Fc3 [X = Cl (I), OMe (II), OFc (III), OBu (IV); Fc = ferrocenyl] were obtained by treating WOCl4 with ferrocenyllithium in THF. Reaction of WOCl4 with a threefold excess of FcLi gives I, which may be converted into II using KOMe. Reaction of WOCl4 with a sixfold excess of FcLi gives a mixture containing III and IV in addition to ferrocene and biferrocene. According to the x-ray crystallog. anal., III has a trigonal-bipyramidal structure with three ferrocenyl ligands occupying the equatorial positions and an axial ferrocenoxy group coordinated trans to the oxo ligand. The three W-C(ferrocenyl) (average 2.092 Å) and the O-C(ferrocenyl) [1.33(1) Å] bond distances are remarkably short. The axial tungsten-oxygen distances correspond to a W:O double and a W-O single bond, resp. The 1H and 13C NMR spectra of III are temperature dependent because of a hindered rotation of the ferrocenyl ligands around the W-C(ferrocenyl) bonds.

Here is just a brief introduction to this compound(1273-73-0)Electric Literature of C10BrFe, more information about the compound(Bromoferrocene) is in the article, you can click the link below.

Reference:
Thiazolidine – Wikipedia,
Thiazolidine – ScienceDirect.com