Synthetic Route of 108-59-8, Catalysts allow a reaction to proceed via a pathway that has a lower activation energy than the uncatalyzed reaction. 108-59-8, Name is Dimethylmalonate, SMILES is O=C(OC)CC(OC)=O, belongs to thiazolidines compound. In a article, author is Wang, Jun-Ling, introduce new discover of the category.
Syntheses and Crystal Structures of Benzyl Substituted Thiazolidin-2-cyanamide Derivatives
Reaction of thiazolidin-2-cyanamide and substituted benzyl bromide compounds in acetonitrile at room temperature afforded the 3-(2 ‘-substituted benzyl)thiazolidin-2-cyanamide derivatives1-13in good yields. Compounds1-13were characterized by proton nuclear magnetic resonance (H-1 NMR) and infrared spectroscopies, of which the structures of the isomerico-,m-, andp-fluoro derivatives4-6were established by single crystal X-ray crystallography. Compound4crystallizes in the monoclinic space group P2(1)/n, witha = 9.177(19), b = 8.551(18), c = 14.090(3) angstrom, beta= 98.243(3)degrees, and Z = 4. The unit cell of 5 has a monoclinic P2(1)/csymmetry with the cell parametersa = 9.289(2),b = 14.057(4),c = 8.574(2) angstrom, beta= 100.350(3)degrees, and Z = 4. The unit cell of 6 also has a monoclinicP2(1)/csymmetry with the cell parametersa = 9.333(4), b = 14.034(5), c = 8.508(3) angstrom, beta= 99.15(5)degrees, and Z = 4. [GRAPHICS] .
Synthetic Route of 108-59-8, Consequently, the presence of a catalyst will permit a system to reach equilibrium more quickly, but it has no effect on the position of the equilibrium as reflected in the value of its equilibrium constant.I hope my blog about 108-59-8 is helpful to your research.
Reference:
Thiazolidine – Wikipedia,
,Thiazolidine – ScienceDirect.com