Electric Literature of 593-85-1, Enzymes are biological catalysts that produce large increases in reaction rates and tend to be specific for certain reactants and products. 593-85-1, Name is guanidinecarbonate, SMILES is NC(=N)N.NC(=N)N.OC(=O)O, belongs to thiazolidines compound. In a article, author is Saini, Kapil Mohan, introduce new discover of the category.
On Water: Metal-Free Synthesis of Highly Functionalized Benzothiazolylidene from ortho-Haloanilines
An environmentally benign, transition-metal-free organic base promoted one-pot cascade synthesis of highly functionalized benzo[d]thiazol-2(3H)-ylidene benzamide in the presence of water was accomplished by three-component reaction of ortho-iodoanilines, acrylates, and aroyl isothiocyanates. The protocol involves the in situ generation of thiourea intermediate followed by triethylamine induced intramolecular SNAr displacement reaction and subsequent Michael addition onto acrylate leads to the formation of benzo[d]thiazol-2(3H)-ylidene benzamide. Benzo[b]thiazole is also generated in good yields using amidation and intramolecular aromatic nucleophilic substitution chemistry. The control experiments support the proposed mechanistic pathway. Further X-ray crystallographic studies confirmed the assigned structures of the fused benzamide.
Electric Literature of 593-85-1, Enzymes are biological catalysts that produce large increases in reaction rates and tend to be specific for certain reactants and products. I hope my blog about 593-85-1 is helpful to your research.
Reference:
Thiazolidine – Wikipedia,
,Thiazolidine – ScienceDirect.com