Synthetic Route of C9H13NO2. The reaction of aromatic heterocyclic molecules with protons is called protonation. Aromatic heterocycles are more basic than benzene due to the participation of heteroatoms. Compound: Ethyl 3,5-Dimethyl-2-pyrrolecarboxylate, is researched, Molecular C9H13NO2, CAS is 2199-44-2, about Molecular Rectangle Formed by Head-to-tail Self-Assembly of 1-(Dipyrrin-2-yl)-1′-(dipyrrin-3-yl)methane. Author is Yang, Lanying; Zhang, Yi; Chen, Qingqi; Ma, Jin Shi.
1-(Dipyrrin-2-yl)-1′-(dipyrrin-3-yl)methane (I), the N-confused analog of biladiene-ac, was prepared by condensation of 2,3′-dipyrromethane with two mols. of 2-formylpyrrole in CH2Cl2 in the presence of HBr. Self-assembly of the ligand with Zn(II) in CH2Cl2 and MeOH offers a dinuclear dimeric complex with a ligand:metal ratio of 2:2. X-ray crystal structure anal. reveals two ligands bound through a head-to-tail pattern to two Zn centers to form a severely distorted helical conformation, which has the shape of a rectangle.
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Reference:
Thiazolidine – Wikipedia,
Thiazolidine – ScienceDirect.com