Most of the compounds have physiologically active properties, and their biological properties are often attributed to the heteroatoms contained in their molecules, and most of these heteroatoms also appear in cyclic structures. A Journal, Article, Research Support, N.I.H., Extramural, Journal of the American Chemical Society called Alkenyl Carbonyl Derivatives in Enantioselective Redox Relay Heck Reactions: Accessing α,β-Unsaturated Systems, Author is Zhang, Chun; Santiago, Celine B.; Kou, Lei; Sigman, Matthew S., which mentions a compound: 1428537-19-2, SMILESS is FC(C1=CN=C(C2=N[C@H](C(C)(C)C)CO2)C=C1)(F)F, Molecular C13H15F3N2O, Safety of (R)-4-(tert-Butyl)-2-(5-(trifluoromethyl)pyridin-2-yl)-4,5-dihydrooxazole.
A highly enantioselective and site-selective Pd-catalyzed arylation of alkenes linked to carbonyl derivatives to yield α,β-unsaturated systems is reported. The high site selectivity is attributed to both a solvent effect and the polarized nature of the carbonyl group, both of which have been analyzed through multidimensional anal. tools. The reaction can be performed in an iterative fashion allowing for a diastereoselective installation of two aryl groups along an alkyl chain.
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Reference:
Thiazolidine – Wikipedia,
Thiazolidine – ScienceDirect.com