The preparation of ester heterocycles mostly uses heteroatoms as nucleophilic sites, which are achieved by intramolecular substitution or addition reactions. Compound: Bromoferrocene( cas:1273-73-0 ) is researched.Electric Literature of C10BrFe.Zhang, Lei; Liu, Jin-ting published the article 《Synthesis and crystal structure of single butterfly-shaped cluster [(μ-FcS)(μ-SMe)Fe2(CO)6]》 about this compound( cas:1273-73-0 ) in Hecheng Huaxue. Keywords: hydrogenase mimic sulfur iron ferrocene crystal mol structure; crystal mol structure carbonyl ferrocenylsulfido methylsulfido iron preparation. Let’s learn more about this compound (cas:1273-73-0).
A novel single butterfly-shaped cluster, (μ-FcS)(μ-SMe)Fe2(CO)6 (1), was synthesized by the reaction of ferrocenyl Mg bromide (FcMgBr) with (μ-S2)Fe2(CO)6 and MeI. The structure was characterized by 1H NMR, IR, elemental anal. and x-ray single crystal diffraction. Comples 1 belongs to orthorhombic space group Pna21 with a 12.707(2), b 11.355(2), c 27.621(5) Å, V = 3,985.1(12) Å3, Z = 8, Dc = 1.813 g cm-3, μ = 2.395 mm-1, F(000) = 2,176, R1 = 0.059 7, wR2 = 0.136 7.
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Reference:
Thiazolidine – Wikipedia,
Thiazolidine – ScienceDirect.com