The chemical properties of alicyclic heterocycles are similar to those of the corresponding chain compounds. Compound: Ethyl 3,5-Dimethyl-2-pyrrolecarboxylate, is researched, Molecular C9H13NO2, CAS is 2199-44-2, about Biosynthesis of porphyrins and related macrocycles. Part 25. Synthesis of analogs of coproporphyrinogen-III and studies of their interaction with coproporphyrinogen-III oxidase from Euglena gracilis, the main research direction is coproporphyrinogen III analog preparation decarboxylation enzyme; oxidase coproporphyrinogen III Euglena substrate selectivity; protoporphyrinogen IX formation coproporphyrinogen III mechanism.Safety of Ethyl 3,5-Dimethyl-2-pyrrolecarboxylate.
Coproporphyrinogen III analogs I [R = (CH2)3CO2H, R1 = (CH2)2CO2H; R = (CH2)2CO2H, R1 = (CH2)3CO2H, (CH2)2CO2Me; R = (CH2)2CO2Me, R1 = (CH2)2CO2H] (II-V, resp.) were prepared Coproporphyrinogen III oxidase from E. gracilis acted on III and IV, which have normal substituents on the A-ring, to generate a vinyl group on that ring. The enzyme has no effect on II and V, where the A-ring propionic acid group has been changed. The implications of this in the biosynthesis of protoporphyrinogen IX from coproporphyrinogen III are briefly discussed. Conditions have been defined for the MacDonald synthesis of porphyrins which yield products of high isomeric purity.
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Reference:
Thiazolidine – Wikipedia,
Thiazolidine – ScienceDirect.com