Little discovery in the laboratory: a new route for 1273-73-0

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Herberhold, Max; Ellinger, Max; Kremnitz, Walter published the article 《Ferrocenylamines》. Keywords: ferrocenylamine; amine ferrocenyl.They researched the compound: Bromoferrocene( cas:1273-73-0 ).Safety of Bromoferrocene. Aromatic heterocyclic compounds can be divided into two categories: single heterocyclic and fused heterocyclic. In addition, there is a lot of other information about this compound (cas:1273-73-0) here.

A general method for the preparation of ferrocenylamines involves the reactions of ferrocenyl bromide, FcBr, with the Na salt of an amine or amide in the presence of copper(I) bromide/pyridine. The syntheses of diferrocenylphenylamine and triferrocenylamine, NFc2Ph and NFc3, resp., are reported, and the hydrolysis of N-ferrocenylacetamide to give ferrocenylamine, NH2Fc, is described. The system of the ferrocenyl- and/or phenyl-substituted derivatives of ammonia, NFcnX3-n (n = 0-3; X = H, Ph), is characterized on the basis of mass, UV, visible, and 1H and 13C NMR spectra.

Compounds in my other articles are similar to this one(Bromoferrocene)Safety of Bromoferrocene, you can compare them to see their pros and cons in some ways,such as convenient, effective and so on.

Reference:
Thiazolidine – Wikipedia,
Thiazolidine – ScienceDirect.com