The three-dimensional configuration of the ester heterocycle is basically the same as that of the carbocycle. Compound: Bromoferrocene(SMILESS: Br[C-]12[Fe+2]3456789([C-]%10C6=C7C8=C9%10)C1=C3C4=C25,cas:1273-73-0) is researched.Electric Literature of C10BrFe. The article 《Isolation, characterization, and synthetic utility of several solid organolithium compounds》 in relation to this compound, is published in Journal of Organometallic Chemistry. Let’s take a look at the latest research on this compound (cas:1273-73-0).
Pentachlorophenyllithium and ferrocenyllithium were isolated and characterized as relatively air-stable solids. The chem. reactivity of these organolithium compounds was investigated, and several carbene complexes of Cr and W were prepared Pentachlorophenyllithium adds to furan and therefore represents a solid benzyne precursor. 1,1′-Dilithioferrocene.2TMEDA (TMEDA = N,N,N’,N’-tetramethylethylenediamine), ferrocenyllithium. TMEDA, and 2-lithio[(dimethylamino)methyl]-ferrocene were isolated and characterized as air-sensitive solids. An attempted formation of 2,2′-dilithiobiphenyl from 2,2′-dibromobiphenyl and BuLi yielded a mixture of ∼80% of this dilithium reagent and ca. 20% of 2-bromo-2′-lithiobiphenyl.
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Reference:
Thiazolidine – Wikipedia,
Thiazolidine – ScienceDirect.com