Epoxy compounds usually have stronger nucleophilic ability, because the alkyl group on the oxygen atom makes the bond angle smaller, which makes the lone pair of electrons react more dissimilarly with the electron-deficient system. Compound: Bromoferrocene, is researched, Molecular C10BrFe, CAS is 1273-73-0, about Synthesis, chemical reactivity and electrochemical behaviour of mono- and difluoro metallocenes.Related Products of 1273-73-0.
Syntheses of mono- and 1,1′-difluoro-substituted metallocenes (ferrocene, ruthenocene) and of asym. 1,1′-disubstituted ferrocenes with one substituent being fluorine are described. Lithiation of metallocenes and subsequent addition of the fluorinating agent NFSI gave the fluorinated metallocenes after optimization of the exptl. conditions. All new compounds were comprehensively characterized and the cyclic voltammograms of fluoro- and 1,1′-difluoroferrocene were recorded and compared to other mono- and dihalogenated ferrocenes. Half-wave potentials of +106 mV and +220 mV vs. FcH0/+ were obtained for monofluorinated species and difluorinated ferrocene, resp. Both values are remarkably low compared to the other halogenated ferrocenes (Cl, Br, and I). Finally, 1-bromo-1′-fluoro-ferrocene turns out to be an ideal starting material for further fluoro-substituted ferrocene derivatives
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Reference:
Thiazolidine – Wikipedia,
Thiazolidine – ScienceDirect.com