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Stereoselective and Catalytic Synthesis of anti-beta-Alkoxy-alpha-azido Carboxylic Derivatives
Direct addition of a chiral N-azidoacetyl thiazolidinethione to a variety of dialkyl acetals catalyzed by a commercially available and structurally simple nickel(II) complex gives access in good yields and a highly stereocontrolled manner to anti-beta-alkoxy-alpha-azido carboxylic derivatives which, in turn, can be easily converted into a wide array of enantiomerically pure compounds.
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Quinuclidine – Wikipedia,
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