Extracurricular laboratory: Synthetic route of 94-41-7

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Computed Properties of C15H12O. Wu, YF; Tang, XF; Zhao, JN; Ma, CF; Yun, L; Yu, ZY; Song, B; Meng, QW in [Wu, Yufeng; Tang, Xiaofei; Zhao, Jingnan; Ma, Cunfei; Yun, Lei; Yu, Zongyi; Song, Bo; Meng, Qingwei] Dalian Univ Technol, Dalian, Peoples R China published Sustainable and Practical Access to Epoxides: Metal-Free Aerobic Epoxidation of Olefins Mediated by Peroxy Radical Generated In Situ in 2020.0, Cited 46.0. The Name is Chalcone. Through research, I have a further understanding and discovery of 94-41-7.

A sustainable and practical protocol to prepare epoxides has been established by using air as the oxidant in the presence of K2CO3 in isopropylbenzene (CM) at 80-140 degrees C. The olefins are successfully converted into their corresponding epoxides in yields of up to 99%. CM and K2CO3 are reused in the scale-up recycling experiments. A reaction mechanism dominated by the radical pathway is proposed according to the control experiments and kinetic analysis.

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Reference:
Thiazolidine – Wikipedia,
,Thiazolidine – ScienceDirect.com