Extracurricular laboratory: Synthetic route of 1273-73-0

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Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 1273-73-0, is researched, SMILESS is Br[C-]12[Fe+2]3456789([C-]%10C6=C7C8=C9%10)C1=C3C4=C25, Molecular C10BrFeJournal, Chemistry Letters called Structure of stable telluradiphosphirane bearing bulky ferrocenyl ligands, Author is Sasamori, Takahiro; Suzuki, Yuko; Sakagami, Michiyasu; Miyake, Hideaki; Tokitoh, Norihiro, the main research direction is stable bulky ferrocenyl thiadiphosphirane telluradiphosphirane preparation crystal mol structure; bis ferrocenyl diphosphene chalcogenation.Quality Control of Bromoferrocene.

Chalcogenation reactions of 1,2-bis(ferrocenyl)diphosphene, Fc*P:PFc* (Fc* = 2,5-bis(3,5-di-t-butylphenyl)ferrocenyl), with elemental sulfur (S8) and tellurium afforded the corresponding thia- and telluradiphosphirane derivatives as stable crystalline compounds, resp. The sterically demanding ferrocenyl group would afford sufficient crystallinity and stability to the heterocyclic compounds; the structures of these three-membered ring heterocycles were revealed by x-ray crystallog. anal.

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Reference:
Thiazolidine – Wikipedia,
Thiazolidine – ScienceDirect.com