The three-dimensional configuration of the ester heterocycle is basically the same as that of the carbocycle. Compound: Bromoferrocene(SMILESS: Br[C-]12[Fe+2]3456789([C-]%10C6=C7C8=C9%10)C1=C3C4=C25,cas:1273-73-0) is researched.Safety of Bromoferrocene. The article 《Substituent effects in the iron 2p and carbon 1s edge near-edge x-ray absorption fine structure (NEXAFS) spectroscopy of ferrocene compounds》 in relation to this compound, is published in Journal of Physical Chemistry A. Let’s take a look at the latest research on this compound (cas:1273-73-0).
The iron 2p and carbon 1s near-edge x-ray absorption fine structure (NEXAFS) spectra of substituted ferrocene compounds, Cp2Fe, Cp*2Fe, CpFe(η5-C5H4Me), CpFe(η5-C5H4Br) CpFe(η5-C5H4CO2H) CpFe(η5-C5H4CH:CH2) (η5-C5H4Me)2Fe, (η5-C5H4Br)2Fe, (η5-C5H4CO2H)2Fe, (η5-C5H4COMe)2Fe are reported and are interpreted with the aid of EHMO (EHMO) theory and d. functional theory (DFT). Significant substituent effects are observed in both the Fe 2p and C 1s NEXAFS spectra. These effects can be related to the electron donating/withdrawing properties of the cyclopentadienyl ligands and their substituents as well as the presence of π* conjugation between the cyclopentadienyl ligand and unsaturated substituents.
Compound(1273-73-0)Reference of Bromoferrocene received a lot of attention, and I have introduced some compounds in other articles, similar to this compound(Bromoferrocene), if you are interested, you can check out my other related articles.
Reference:
Thiazolidine – Wikipedia,
Thiazolidine – ScienceDirect.com