Carre, Francis; Guerin, Christian; Henner, Bernard J. L.; Uerpmann, Carsten published an article about the compound: Bromoferrocene( cas:1273-73-0,SMILESS:Br[C-]12[Fe+2]3456789([C-]%10C6=C7C8=C9%10)C1=C3C4=C25 ).Electric Literature of C10BrFe. Aromatic heterocyclic compounds can be classified according to the number of heteroatoms or the size of the ring. The authors also want to convey more information about this compound (cas:1273-73-0) through the article.
The synthesis of 1,1′-bis(N-tert-butyl-N-hydroxyamino)ferrocene (1) is described, and the x-ray anal. showed eclipsed positions of the two tert-butylhydroxyamino groups. This structure can be explained by the interactions of the hydroxyl hydrogens with the N atoms of the other tert-butylhydroxyamino group. This interaction is maintained in solution and may explain that the oxidation of 1 using Ag2O gave a decomposition reaction instead of the expected 1,1′-bis(N-tert-butylaminoxy)ferrocene. The ESR spectrum of an oxidized solution of 1 showed a 1:1:1 triplet, but it corresponded only to traces of an N-O• radical. Cyclic voltammograms of 1 showed that it is more easily oxidized than ferrocene and less easily than 1,1′-diaminoferrocene, indicating that chem. oxidation of 1 occurs in the ferrocenyl part of the mol., followed by rapid decomposition
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Reference:
Thiazolidine – Wikipedia,
Thiazolidine – ScienceDirect.com