The three-dimensional configuration of the ester heterocycle is basically the same as that of the carbocycle. Compound: Bromoferrocene(SMILESS: Br[C-]12[Fe+2]3456789([C-]%10C6=C7C8=C9%10)C1=C3C4=C25,cas:1273-73-0) is researched.Application In Synthesis of 3,4-Dihydroisoquinoline. The article 《Synthesis, chemical reactivity and electrochemical behaviour of mono- and difluoro metallocenes》 in relation to this compound, is published in Journal of Organometallic Chemistry. Let’s take a look at the latest research on this compound (cas:1273-73-0).
Syntheses of mono- and 1,1′-difluoro-substituted metallocenes (ferrocene, ruthenocene) and of asym. 1,1′-disubstituted ferrocenes with one substituent being fluorine are described. Lithiation of metallocenes and subsequent addition of the fluorinating agent NFSI gave the fluorinated metallocenes after optimization of the exptl. conditions. All new compounds were comprehensively characterized and the cyclic voltammograms of fluoro- and 1,1′-difluoroferrocene were recorded and compared to other mono- and dihalogenated ferrocenes. Half-wave potentials of +106 mV and +220 mV vs. FcH0/+ were obtained for monofluorinated species and difluorinated ferrocene, resp. Both values are remarkably low compared to the other halogenated ferrocenes (Cl, Br, and I). Finally, 1-bromo-1′-fluoro-ferrocene turns out to be an ideal starting material for further fluoro-substituted ferrocene derivatives
There is still a lot of research devoted to this compound(SMILES：Br[C-]12[Fe+2]3456789([C-]%10C6=C7C8=C9%10)C1=C3C4=C25)Computed Properties of C10BrFe, and with the development of science, more effects of this compound(1273-73-0) can be discovered.
Reference:
Thiazolidine – Wikipedia,
Thiazolidine – ScienceDirect.com