An article Synthesis and evaluation of new tri- and difluoromethyl containing 2,6,9-trioxabicyclo[3.3.1]nonanes WOS:000473121000013 published article about ONE-STEP SYNTHESIS; ABSOLUTE-CONFIGURATION; ETHERS; FLUORINE; FACILE in [Gerus, Igor I.; Zhuk, Yury, I; Tarasenko, Karen, V; Shaitanova, Elena N.; Sorochinskii, Alexandr E.] Natl Ukrainian Acad Sci, Inst Bioorgan Chem & Petrochem, Dept Fine Organ Synth, Murmanska Str 1, UA-02094 Kiev, Ukraine in 2019.0, Cited 26.0. Application In Synthesis of 1,1,1-Triethoxyethane. The Name is 1,1,1-Triethoxyethane. Through research, I have a further understanding and discovery of 78-39-7
Enones 1, are examples of available and attractive building block which already has the polyfluoroalkyl group in blocks skeleton and their functionalization is an actual and perspective approach for the synthesis of more functionalized molecules. This approach led us to new polyfluoroalkyl containing trioxabicyclo[3.3.1]nona-3,7-diene-4,8-dicarboxylates with four trifluoromethyl or two trifluoromethyl and two difluoromethyl groups in moderate yields (up to 68%). These compounds are perspective as synthetic intermediates for preparation of new polyfluoromethyl containing heterocycles as well as their interaction into macrocycles system like crown ethers.
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Reference:
Thiazolidine – Wikipedia,
,Thiazolidine – ScienceDirect.com