Continuously updated synthesis method about 1273-73-0

Compound(1273-73-0)Safety of Bromoferrocene received a lot of attention, and I have introduced some compounds in other articles, similar to this compound(Bromoferrocene), if you are interested, you can check out my other related articles.

Safety of Bromoferrocene. So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic. Compound: Bromoferrocene, is researched, Molecular C10BrFe, CAS is 1273-73-0, about Cofacial metallocenes. Synthesis and crystal structure of 1,8-diferrocenylnaphthalene.

The optimal synthesis of 1,8-differocenylnaphthalene (I) was the coupling of 1,8-diiodonaphthalene and ferrocenylzinc chloride in the presence of ferrocenylphosphine-containing catalyst PdLCl2, giving 58% of I with 94% selectivity. The x-ray crystal structure of I showed that the naphthalene ring and bonds from the peri-C atoms to the cyclopentadienyl rings were highly distorted. The 2 substituted cyclopentadienyl rings were rotated by ∼46° from the perpendicular to the naphthalene ring. Cyclic voltammetry of I showed 2 reversible, one-electron waves. The monocation I+BF4- derived by oxidation of I with AgBF4, had an intervalence transfer band at 1600 nm (εmax 200), not shown by the corresponding dication of I. I+ was best represented as a weakly interacting mixed-valence system.

Compound(1273-73-0)Safety of Bromoferrocene received a lot of attention, and I have introduced some compounds in other articles, similar to this compound(Bromoferrocene), if you are interested, you can check out my other related articles.

Reference:
Thiazolidine – Wikipedia,
Thiazolidine – ScienceDirect.com