Category: thiazolidines. I found the field of Chemistry very interesting. Saw the article Palladium-Catalyzed Oxidative Coupling of the Allenic C-H Bond with alpha-Diazo Esters: Synthesis of [3]Dendralenes published in 2021.0, Reprint Addresses Wang, JB (corresponding author), Peking Univ, Coll Chem, Beijing Natl Lab Mol Sci BNLMS, Key Lab Bioorgan Chem & Mol Engn,Minist Educ, Beijing 100871, Peoples R China.. The CAS is 78-39-7. Through research, I have a further understanding and discovery of 1,1,1-Triethoxyethane.
A palladium-catalyzed highly regio- and stereoselective allenic C-H oxidative coupling with alpha-diazo esters is developed. The reaction pathway involves allylic palladium carbene as the key intermediate, which is followed by a carbene migratory insertion process. The reaction proceeds efficiently under mild conditions without external base, providing substituted [3]dendralenes bearing various functional groups.
Category: thiazolidines. About 1,1,1-Triethoxyethane, If you have any questions, you can contact Li, SC; Hou, B; Wang, JB or concate me.
Reference:
Thiazolidine – Wikipedia,
,Thiazolidine – ScienceDirect.com