The preparation of ester heterocycles mostly uses heteroatoms as nucleophilic sites, which are achieved by intramolecular substitution or addition reactions. Compound: Bromoferrocene( cas:1273-73-0 ) is researched.Application of 1273-73-0.Chambron, Jean Claude; Coudret, Christophe; Sauvage, Jean Pierre published the article 《Synthesis and study of bis-terpyridine iron(II), ruthenium(II) and osmium(II) diad complexes bearing a remote ferrocenyl unit as electron donor》 about this compound( cas:1273-73-0 ) in New Journal of Chemistry. Keywords: metal terpyridine ferrocenyl complex redox electrochem; iron terpyridine complex redox electrochem; osmium terpyridine complex redox electrochem; ruthenium terpyridine complex redox electrochem. Let’s learn more about this compound (cas:1273-73-0).
A new terpyridine ligand (I; Fc-phterpy), containing an electroactive ferrocenyl group, was prepared by using a palladium-catalyzed aromatic cross-coupling reaction. For the corresponding iron(II), ruthenium(II) and osmium(II) homo- and heteroleptic complexes of I, phys. studies (electrochem. and spectroscopy) show a weak interaction between the ferrocenyl group and the M(terpy)2+ center in its ground state. However, evidence of a strong intramol. quenching of the excited state of these complexes was obtained in the osmium series.
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Reference:
Thiazolidine – Wikipedia,
Thiazolidine – ScienceDirect.com