Recently I am researching about ALLYLIC ACETATES; MOLECULES, Saw an article supported by the NSFCNational Natural Science Foundation of China (NSFC) [21871010]; Laboratory for Synthetic Chemistry and Chemical Biology under the Health@InnoHK Program by Innovation and Technology Commission, The Government of Hong Kong Special Administrative Region of the People’s Republic of China. Published in AMER CHEMICAL SOC in WASHINGTON ,Authors: Li, SC; Hou, B; Wang, JB. The CAS is 78-39-7. Through research, I have a further understanding and discovery of 1,1,1-Triethoxyethane. COA of Formula: C8H18O3
A palladium-catalyzed highly regio- and stereoselective allenic C-H oxidative coupling with alpha-diazo esters is developed. The reaction pathway involves allylic palladium carbene as the key intermediate, which is followed by a carbene migratory insertion process. The reaction proceeds efficiently under mild conditions without external base, providing substituted [3]dendralenes bearing various functional groups.
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Reference:
Thiazolidine – Wikipedia,
,Thiazolidine – ScienceDirect.com