The reaction of an aromatic heterocycle with a proton is called a protonation. One of articles about this theory is 《Some reactions of halogen derivatives of ferrocene. Ferrocenylamine. Ferrocenyl acetate》. Authors are Nesmeyanov, A. N.; Sazonova, V. A.; Drozd, V. N..The article about the compound:Bromoferrocenecas:1273-73-0,SMILESS:Br[C-]12[Fe+2]3456789([C-]%10C6=C7C8=C9%10)C1=C3C4=C25).Category: thiazolidine. Through the article, more information about this compound (cas:1273-73-0) is conveyed.
cf. C.A. 50, 2558a; 54, 6673h. Refluxing 0.3 g. bromoferrocene (I) with 1 g. Cu(OAc)2 in 30 ml. 50% EtOH 15 min. gave 90% ferrocenyl acetate, m. 64.5-6.5° (EtOH); hydrolysis and treatment with BzCl gave ferrocenyl benzoate, m. 108.5-9.5°. Ferrocenyl acetate was similarly prepared in 84% yield from chloroferrocene. Heating 0.6 g. I with 1.5 g. Cu phthalimide 2 hrs. at 135-40° gave after extraction with Et2O 64% N-ferrocenylphthalimide, m. 156-7° (EtOH); chloroferrocene gave a 53% yield. Refluxing the imide with N2H4.H2O in EtOH under N 40 min. gave after an aqueous treatment 82% ferrocenylamine, m. 153-5°, which with Ac2O in pyridine at room temperature gave 82% N-acetylferrocenylamine, m. 169-71°. Heating I with Cu(CN)2 2 hrs. at 140° gave 84% ferrocenecarbonitrile, m. 105.5-6.5°; the yield was 42% when the reaction was run 3 hrs. in pyridine with chloroferrocene and when a small amount of the nitrile was originally present in the reaction mixture
After consulting a lot of data, we found that this compound(1273-73-0)Category: thiazolidine can be used in many types of reactions. And in most cases, this compound has more advantages.
Reference:
Thiazolidine – Wikipedia,
Thiazolidine – ScienceDirect.com