Archives for Chemistry Experiments of (Z)-But-2-ene-1,4-diol

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A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 6117-80-2, Name is (Z)-But-2-ene-1,4-diol, molecular formula is C4H8O2. In an article, author is Ousidi, Abdellah N’ait,once mentioned of 6117-80-2, Category: thiazolidines.

Crystal structure of 2-[(3aS,6R)-3,3,6-trimethyl-3,3a,4,5,6,7-hexahydro-2H-indazol-2-yl]thiazol-4(5H)-one

The title compound, C13H19N3OS, is a new thiazolidin-4-one derivative prepared and isolated as the pure (3aS,6R)-diastereisomer from (R)-thiosemicarbazone pulegone. It crystallized with two independent molecules (A and B) in the asymmetric unit. The compound is composed of a hexhydroindazole ring system (viz. a five-membered dihydropyrazole ring fused to a cyclohexyl ring) with a thiazole-4-one ring system attached to one of the pyrazole N atoms (at position 2). The overall geometry of the two molecules differs slightly, with the mean planes of the pyrazole and thiazole rings being inclined to one another by 10.4 (1)degrees in molecule A and 0.9 (1)degrees in molecule B. In the crystal, the A and B molecules are linked via C-H center dot center dot center dot O hydrogen bonds, forming slabs parallel to the ab plane. There are C-H center dot center dot center dot pi interactions present within the layers, and between the layers, so forming a three-dimensional structure.

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Reference:
Thiazolidine – Wikipedia,
,Thiazolidine – ScienceDirect.com