Archives for Chemistry Experiments of 94-41-7

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An article Dehydrative C- and S-Alkylation: Access to Highly Substituted 1-Sulfonylpropanes WOS:000466161500019 published article about FRIEDEL-CRAFTS REACTIONS; ALLYLIC ALCOHOLS; NUCLEOPHILIC SUBSTITUTIONS; BENZYLIC ALCOHOLS; ALPHA-ALKYLATION; BOND ACTIVATION; METAL; BENZYLATION; GENERATION; INDOLES in [Aegurla, Balakrishna; Peddinti, Rama Krishna] Indian Inst Technol Roorkee, Dept Chem, Roorkee 247667, Uttarakhand, India in 2019.0, Cited 71.0. The Name is Chalcone. Through research, I have a further understanding and discovery of 94-41-7. Recommanded Product: Chalcone

A dehydrative C- and S-alkylation procedure by nucleophilic substitution of gamma-hydroxysufones with arenes and thiophenols is reported. This study represents an elegant and ecological concept to construct C-C and C-S bonds leading to unsymmetrical 1,1- and 3,3-branched propanes. The gamma-hydroxysufones underwent BF3 center dot OEt2-mediated dehydrative arylation and thiolation at room temperature and elimination at 40 degrees C. The nucleophile attack occurred on the less hindered side of a planar benzylic carbocation to furnish the title compounds with good diastereoselectivity.

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Reference:
Thiazolidine – Wikipedia,
,Thiazolidine – ScienceDirect.com