Archives for Chemistry Experiments of 2199-44-2

When you point to this article, it is believed that you are also very interested in this compound(2199-44-2)Reference of Ethyl 3,5-Dimethyl-2-pyrrolecarboxylate and due to space limitations, I can only present the most important information.

In general, if the atoms that make up the ring contain heteroatoms, such rings become heterocycles, and organic compounds containing heterocycles are called heterocyclic compounds. An article called Complexation between decamethyl-3,3′-bis(dipyrrolylmethene) and zinc(II), copper(II), and cobalt(II) acetates, published in 2009-01-31, which mentions a compound: 2199-44-2, Name is Ethyl 3,5-Dimethyl-2-pyrrolecarboxylate, Molecular C9H13NO2, Reference of Ethyl 3,5-Dimethyl-2-pyrrolecarboxylate.

Decamethylmethylene-3,3′-bis(dipyrrolylmethene) dihydrobromide H2L·2HBr, which is the simplest representative of a novel class of oligo(dipyrrolylmethenes) belonging to chromophore chelating nonmacrocyclic ligands, were examined by 1H NMR, IR, and electronic absorption spectroscopy. Complexation reactions of H2L·2HBr with M(AcO)2 (M = Zn(II), Cu(II), and Co(II)) in DMF at 298.15 K were monitored by electronic absorption spectroscopy and studied by the molar ratio method. The thermodn. constants K0 of these reactions were estimated The d metal ions coordinate H2L to give the binuclear homoleptic complexes [M2L2]. The reactions proceed through the intermediate binuclear heteroleptic complex [M2L(AcO)2] detected by spectroscopic methods. The thermodn. stabilities of [M2L2] and [M2L(AcO)2] increase when moving from Cu(II) to Zn(II) and Co(II). The probability of formation and stability of [M2L2] containing 3,3′-bis(dipyrrolylmethene) are substantially higher than those of analogous complexes with the 2,2′-isomer (decamethyl-2,2′-biladiene-a,c). The low K0 values for the complexation between H2L and Cu(AcO)2 are due to slow oxidation of the biladiene ligand into a bilatriene with participation of Cu2+ ions.

When you point to this article, it is believed that you are also very interested in this compound(2199-44-2)Reference of Ethyl 3,5-Dimethyl-2-pyrrolecarboxylate and due to space limitations, I can only present the most important information.

Reference:
Thiazolidine – Wikipedia,
Thiazolidine – ScienceDirect.com