Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 2199-44-2, is researched, SMILESS is O=C(C1=C(C)C=C(C)N1)OCC, Molecular C9H13NO2Journal, Justus Liebigs Annalen der Chemie called tert-Butylpyrroles, Author is Treibs, Alfred; Schulze, Lothar, the main research direction is butyldimethyl pyrrole; pyrrole butyldimethyl.Name: Ethyl 3,5-Dimethyl-2-pyrrolecarboxylate.
Reaction of 3-(R-substituted)-2,4-dimethylpyrroles (R = CO2Et or Ac) with tert-BuOAc in the presence of strong acids, e.g. H2SO4, HClO4, or HI gave 12-30% corresponding 5-tert-butyl compounds (I). Treatment of I (R = CO2Et) with H3PO4 gave 43% I (R = H). Similar reactions were performed with 5-(ethoxycarbonyl)-2,4-dimethylpyrrole.
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Reference:
Thiazolidine – Wikipedia,
Thiazolidine – ScienceDirect.com