Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 1273-73-0, is researched, SMILESS is Br[C-]12[Fe+2]3456789([C-]%10C6=C7C8=C9%10)C1=C3C4=C25, Molecular C10BrFeJournal, Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya called Ferrocenylgold-triphenylphosphine, Author is Nesmeyanov, A. N.; Perevalova, E. G.; Lemenovskii, D. A.; Kosina, A. N.; Grandberg, K. I., the main research direction is gold ferrocenyl phosphines; ferrocenyl phosphines gold; phosphines gold ferrocenyl; ferrocenes; iron organic compound.Name: Bromoferrocene.
To ferrocenyllithium from 2.8 g ferrocene in THF-Et2O with BuLi under argon was added 2 g ClAuPPh3, and after 2 hr the mixture quenched in H2O to yield 81% orange ferrocenyl-goldtriphenylphosphine, C5H5FeC5H4AuPPh3, decomposed 150°; ir and NMR spectral data given. Chromatog. on Al2O3 decomposed this to ferrocene. BrAuPPh3 in the above reaction gave the same complex in 67% yield. Treated with dry HCl in C6H6 the product gave ferrocene and ClAuPPh3, m. 242-3°; HI gave diferrocenyl in trace amounts along with nearly 100% ferrocene and IAuPPh3, m. 224-5°. HCN similarly converted the complex into ferrocene and AuCN.PPh3, m. 203.5-204°. Bromination gave bromoferrocene, m. 30-1°, and 81% BrAuPPh3. ClAuPPh3 in Et2O under argon treated with BuLi 5 hr gave 86% oily BuAuPPh3, which darkened in air. It was purified by freezing in liquid pentane at -70°.
In some applications, this compound(1273-73-0)Name: Bromoferrocene is unique.If you want to know more details about this compound, you can contact with the author or consult more relevant literature.
Reference:
Thiazolidine – Wikipedia,
Thiazolidine – ScienceDirect.com