In organic chemistry, atoms other than carbon and hydrogen are generally referred to as heteroatoms. The most common heteroatoms are nitrogen, oxygen and sulfur. Now I present to you an article called Rhodium(III) and ruthenium(II) complexes of redox-active, chelating N-heterocyclic carbene/thioether ligands, published in 2011, which mentions a compound: 1273-73-0, mainly applied to crystal structure rhodium ruthenium ferrocenyl NHC thioether complex preparation; mol structure rhodium ruthenium ferrocenyl NHC thioether complex; rhodium ruthenium ferrocenyl NHC thioether complex preparation electrochem property, Product Details of 1273-73-0.
Half-sandwich rhodium(III) and ruthenium(II) complexes bearing a new redox-active ferrocenyl NHC-thioether ligand have been prepared The synthesis of ferrocenyl thioether-imidazolium salts was carried out via intermediate FcSCH2CH2Cl using an improved procedure. Rhodium(III) complex and ruthenium(II) complex were obtained in good yields and were fully characterised by NMR spectroscopy, x-ray diffraction anal. and electrochem. Rhodium(III) complex shows a complex ABCD system by 1H NMR, which denotes conformational rigidity due to the presence of several bulky groups. Electrochem. anal. by cyclic voltammetry reveals reversible redox behavior about the iron center in both complexes, and indicates electronic communication between iron and rhodium or ruthenium.
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Reference:
Thiazolidine – Wikipedia,
Thiazolidine – ScienceDirect.com