Epoxy compounds usually have stronger nucleophilic ability, because the alkyl group on the oxygen atom makes the bond angle smaller, which makes the lone pair of electrons react more dissimilarly with the electron-deficient system. Compound: Bromoferrocene, is researched, Molecular C10BrFe, CAS is 1273-73-0, about Redox-Rich Metallocene Tetrazene Complexes: Synthesis, Structure, Electrochemistry, and Catalysis.Application of 1273-73-0.
Thermal or photochem. metal-centered cycloaddition reactions of azidocobaltocenium hexafluorophosphate or azidoferrocene with (cyclooctadiene)(cyclopentadienyl)Co(I) afforded the first metallocenyl-substituted tetrazene cyclopentadienyl cobalt complexes together with azocobaltocenium or azoferrocene as side products. The trimetallic CpCo compounds are highly conjugated, colored and redox-active metallo-aromatic compounds, as shown by their spectroscopic, structural and electrochem. properties. The CpCo-tetrazenido complex with two terminally appended cobaltocene units catalyzes electrochem. proton reduction from acetic acid at a mild overpotential (0.35 V). Replacing cobaltocene with ferrocene moieties rendered the complex inactive toward catalysis.
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Reference:
Thiazolidine – Wikipedia,
Thiazolidine – ScienceDirect.com