A new application about 1273-73-0

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Application of 1273-73-0. The protonation of heteroatoms in aromatic heterocycles can be divided into two categories: lone pairs of electrons are in the aromatic ring conjugated system; and lone pairs of electrons do not participate. Compound: Bromoferrocene, is researched, Molecular C10BrFe, CAS is 1273-73-0, about 1-(1′-Bromoferrocenyl)silver. Author is Nesmeyanov, A. N.; Sazonova, N. S.; Sazonova, V. A.; Meskhi, L. M..

Treating 0.5 g 1-bromo-1′-ferroceneboronic acid with Ag2O from 0.5 g Ag NO3 in NH4OH and heating briefly gave 53% 1-(1′-bromoferrocenyl)-silver, decomposed 125-6°. This with concentrated HCl 10 min gave 70% bromoferrocene, while pyrolysis in xylene gave a Ag mirror and 60% bis(1′-bromoferrocenyl), m. 138-40°. Treated with HgBr2 in C6H6 the Ag salt gave 80% 1-(1′-bromoferrocenyl)-mercuric bromide, m. 143-5°. The Ag derivative and BiBr3 in C6H6 in 3-4 hrs gave bromoferrocene and 50% tris(1′-bromoferrocenyl)bismuth, m. 179.5-81°. This kept in concentrated HCl 0.5 hr, then treated with aqueous NH4OH to neutrality, then percolated with H2S, gave a precipitate which was used for estimation of Bi after washing and drying to constant weight

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Reference:
Thiazolidine – Wikipedia,
Thiazolidine – ScienceDirect.com