The effect of reaction temperature change on equilibrium 1273-73-0

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Postnov, V. N.; Klimova, E. I.; Meleshonkova, N. N.; Bolesov, I. G. published the article 《Ring opening of ferrocenyl-substituted cyclopropanes》. Keywords: cyclopropane ferrocenyl ring cleavage; butadiene cationic ferrocenyl formation cyclodimerization.They researched the compound: Bromoferrocene( cas:1273-73-0 ).Recommanded Product: 1273-73-0. Aromatic heterocyclic compounds can be divided into two categories: single heterocyclic and fused heterocyclic. In addition, there is a lot of other information about this compound (cas:1273-73-0) here.

Treating a mixture of isomeric ferrocenyl-substituted cyclopropanes I (R = Fc throughout this abstract) with excess Ph3CBF4 in CH2Cl2 gave a 2:1 mixture of endo and exo isomers of diferrocenyl-substituted cyclohexene II, formed by cyclodimerization of the initially formed butadiene. Cleavage of 3-methyl-3-ferrocenylcyclopropene with CF3CO2H followed by trapping with excess Me2NPh gave a mixture of E- and Z-4-Me2NC6H4CH2CH:CRMe. A mechanism involving ferrocenyl-stabilized carbocation formation is proposed.

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Reference:
Thiazolidine – Wikipedia,
Thiazolidine – ScienceDirect.com