The preparation of ester heterocycles mostly uses heteroatoms as nucleophilic sites, which are achieved by intramolecular substitution or addition reactions. Compound: Bromoferrocene( cas:1273-73-0 ) is researched.Computed Properties of C10BrFe.Sato, Masaru; Motoyama, Izumi; Hata, Kazuo published the article 《Reactions of haloferrocenes. III. Reaction of haloferrocenes with copper(I) benzenethiolate, thiocyanate, acetate, and benzoate》 about this compound( cas:1273-73-0 ) in Bulletin of the Chemical Society of Japan. Keywords: haloferrocenes copper compound; copper compound haloferrocenes; ferrocenes halo copper compound; iodoferrocenes copper compound; iron organic compound. Let’s learn more about this compound (cas:1273-73-0).
Iodoferrocene reacted with copper(I) benzenethiolate in boiling pyridine to give ferrocenyl Ph sulfide in a quant. yield. The reaction of iodoferrocene with copper(I) thiocyanate gave diferrocenyl disulfide. The behavior of copper(I) acetate and benzoate toward haloferrocene was different from those of the other copper(I) salts: reactions in boiling pyridine gave the corresponding ferrocenyl ester, together with a small quantity of ferrocene, while the reaction in boiling toluene produced biferrocenyl as the main product. The reaction mechanism of the ferrocenyl ester and biferrocenyl formations was discussed.
Here is just a brief introduction to this compound(1273-73-0)Computed Properties of C10BrFe, more information about the compound(Bromoferrocene) is in the article, you can click the link below.
Reference:
Thiazolidine – Wikipedia,
Thiazolidine – ScienceDirect.com