He, J; Jia, ZZ; Tan, HC; Luo, XH; Qiu, DC; Shi, JR; Xu, H; Li, Y in [He, Jia; Jia, Zizi; Tan, Hongcheng; Luo, Xiaohua; Qiu, Dachuan; Shi, Jiarong; Xu, Hai; Li, Yang] Chongqing Univ, Sch Chem & Chem Engn, 174 Shazheng St, Chongqing 400030, Peoples R China published Arene Trifunctionalization with Highly Fused Ring Systems through a Domino Aryne Nucleophilic and Diels-Alder Cascade in 2019.0, Cited 75.0. Formula: C8H18O3. The Name is 1,1,1-Triethoxyethane. Through research, I have a further understanding and discovery of 78-39-7.
A convenient and efficient domino aryne process was developed under transition-metal-free conditions to generate a range of tetra- and pentacyclic ring systems. This transformation was realized via a 1,2-benzdiyne through a nucleophilic and Diels-Alder reaction cascade using styrene as the diene moiety. Three new chemical bonds, namely one C-N and two C-C bonds, and two benzofused rings could be constructed concomitantly, which was made possible by distinct chemoselective control at both the 1,2-aryne and 2,3-aryne stages. Moreover, in-depth studies were carried out on the domino aryne precursors and controlling the diastereoselectivity.
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Reference:
Thiazolidine – Wikipedia,
,Thiazolidine – ScienceDirect.com