An article Synthesis of Highly Substituted Pyridines via [4+2] Cycloadditions of Vinylallenes and Sulfonyl Cyanides WOS:000508468900024 published article about DIELS-ALDER REACTIONS; INVERSE ELECTRON-DEMAND; CATALYZED 2+2+2 CYCLOADDITION; IPSO-SUBSTITUTION; BUILDING-BLOCKS; DERIVATIVES; ALLENE; CONSTRUCTION; REACTIVITY; ALKYNES in [Bartko, Samuel G.; Hamzik, Phillip J.; Espindola, Leandro; Gomez, Christian; Danheiser, Rick L.] MIT, Dept Chem, Cambridge, MA 02139 USA in 2020.0, Cited 108.0. Product Details of 78-39-7. The Name is 1,1,1-Triethoxyethane. Through research, I have a further understanding and discovery of 78-39-7
A convergent strategy for the synthesis of multi-substituted pyridines is described. Vinylallenes combine with commercially available arylsulfonyl cyanides in Diels-Alder cycloadditions to generate isopyridine cycloadducts that are converted to pyridines upon further heating or addition of a base. The 2-sulfonylpyridine products undergo nucleophilic aromatic substitution reactions with oxygen and carbon nucleophiles to provide access to a variety of highly substituted pyridines.
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Reference:
Thiazolidine – Wikipedia,
,Thiazolidine – ScienceDirect.com