Quality Control of 1,1,1-Triethoxyethane. Recently I am researching about CONJUGATE ADDITION; UNACTIVATED ALKENES; CARBONYL-COMPOUNDS; ALPHA-ARYLATION; ARYL HALIDES; ENONES; PD; IODIDES; OLEFINS; HYDROCARBOFUNCTIONALIZATION, Saw an article supported by the National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21602104]; Natural Science Foundation of Jiangsu Province, ChinaNatural Science Foundation of Jiangsu Province [BK 20160986]; Nanjing Tech University [3983500176]. Published in AMER CHEMICAL SOC in WASHINGTON ,Authors: Guo, T; Ding, YL; Zhou, LL; Xu, HY; Loh, TP; Wu, XJ. The CAS is 78-39-7. Through research, I have a further understanding and discovery of 1,1,1-Triethoxyethane
A general intermolecular anti-Michael reductive Heck reaction of alpha,beta-unsaturated esters with organobromides has been developed. Most topical classes of aryl, heteroaryl, and vinyl bromides were found to efficiently react with a variety of internal conjugated alkenes. This protocol set up a platform toward diverse alpha-arylated 1,6-dicarbonyl frameworks found in natural products and drugs, which are still highly challenging targets in traditional alpha-arylation protocols because of competitive selectivity of enolation. A removable directing group, gram-scale reaction, and modification of complex molecules have additionally demonstrated that the anti-Michael reductive Heck reaction is a powerful complementary strategy to the classical alpha-arylation approaches. Preliminary mechanistic studies are consistent with our proposed mechanistic design.
Quality Control of 1,1,1-Triethoxyethane. Welcome to talk about 78-39-7, If you have any questions, you can contact Guo, T; Ding, YL; Zhou, LL; Xu, HY; Loh, TP; Wu, XJ or send Email.
Reference:
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