Quality Control of 1,1,1-Triethoxyethane. Li, MB; Grape, ES; Backvall, JE in [Li, Man-Bo; Backvall, Jan-E.] Stockholm Univ, Dept Organ Chem, Arrhenius Lab, SE-10691 Stockholm, Sweden; [Grape, Erik Svensson] Stockholm Univ, Dept Mat & Environm Chem, Arrhenius Lab, SE-10691 Stockholm, Sweden published Palladium-Catalyzed Stereospecific Oxidative Cascade Reaction of Allenes for the Construction of Pyrrole Rings: Control of Reactivity and Selectivity in 2019.0, Cited 57.0. The Name is 1,1,1-Triethoxyethane. Through research, I have a further understanding and discovery of 78-39-7.
A palladium-catalyzed oxidative cascade reaction of alpha-tosylamide allenes has been developed. The reactivity of the allenes is controlled by the tosylamide group. In the presence of terminal alkynes the reaction proceeds via a pathway leading to a one-pot construction of pyrrole rings. Moreover, a solvent-controlled chemoselectivity of the cascade reaction was realized, leading to a stereospecific and divergent synthesis of (Z)-tetrasubstituted olefins, 2,5-dihydropyrroles, and pyrroles. Enantioenriched (Z)-tetrasubstituted olefins and 2,5-dihydropyrroles are readily synthesized by chirality transfer using this approach.
Quality Control of 1,1,1-Triethoxyethane. Bye, fridends, I hope you can learn more about C8H18O3, If you have any questions, you can browse other blog as well. See you lster.
Reference:
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