Product Details of 94-41-7. Recently I am researching about CATALYTIC ASYMMETRIC HYDROGENATION; P-N-P’; IRON(II) COMPLEXES; COBALT COMPLEXES; WELL, Saw an article supported by the F. Hoffmann-La Roche AGHoffmann-La Roche; Leibniz Foundation (Leibniz Competition) [SAW-2016-LIKAT-1]. Published in WILEY-V C H VERLAG GMBH in WEINHEIM ,Authors: Garbe, M; Wei, ZH; Tannert, B; Spannenberg, A; Jiao, HJ; Bachmann, S; Scalone, M; Junge, K; Beller, M. The CAS is 94-41-7. Through research, I have a further understanding and discovery of Chalcone
The synthesis of different metal pincer complexes coordinating to the chiral PNP ligand bis(2-((2R,5R)-2,5-dimethyl-phospholanoethyl))amine is described in detail. The characterized complexes with Mn, Fe, Re and Ru as metal centers showed good activities regarding the reduction of several prochiral ketones. Comparing these catalysts, the non-noble metal complexes produced best selectivities not only for aromatic substrates, but also for different kinds of aliphatic ones leading to enantioselectivities up to 99% ee. Theoretical investigations elucidated the mechanism and rationalized the selectivity.
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Reference:
Thiazolidine – Wikipedia,
,Thiazolidine – ScienceDirect.com