Safety of 1,1,1-Triethoxyethane. I found the field of Chemistry very interesting. Saw the article Iridium-Catalyzed gamma-Selective Hydroboration of gamma-Substituted Allylic Amides published in 2020.0, Reprint Addresses Zhang, PK (corresponding author), Zhengzhou Univ, Coll Chem, Green Catalysis Ctr, Henan Adv Inst Technol, Zhengzhou 450001, Henan, Peoples R China.; Xu, SM (corresponding author), Chinese Acad Sci, Ctr Excellence Mol Sci, Suzhou Res Inst, Lanzhou Inst Chem Phys,State Key Lab Oxo Synth &, Lanzhou 730000, Gansu, Peoples R China.; Xu, SM (corresponding author), Hangzhou Normal Univ, Key Lab Organosilicon Chem & Mat Technol, Minist Educ, Hangzhou 311121, Peoples R China.; Xu, SM (corresponding author), Univ Chinese Acad Sci, Beijing 100049, Peoples R China.. The CAS is 78-39-7. Through research, I have a further understanding and discovery of 1,1,1-Triethoxyethane.
Reported here for the first time is the Ir-catalyzed gamma-selective hydroboration of gamma-substituted allylic amides under mild reaction conditions. A variety of functional groups could be compatible with reaction conditions, affording gamma-branched amides in good yields with <= 97% gamma-selectivity. We have also demonstrated that the obtained borylated products could be used in a series of C-O, C-F, C-Br, and C-C bond-forming reactions. Safety of 1,1,1-Triethoxyethane. About 1,1,1-Triethoxyethane, If you have any questions, you can contact Zhao, HL; Gao, Q; Zhang, YJ; Zhang, PK; Xu, SM or concate me.
Reference:
Thiazolidine – Wikipedia,
,Thiazolidine – ScienceDirect.com